Much to my surprise, I stumbled across this article on the 2006 release of a college baseball video game. (Thanks to the Rosenblatt Report and Section B, Florida State's fan site.) EA Sports, a big name in the industry, is behind the project. I'm confident that the game will have some shortcomings, as it's an initial effort, however I am encouraged to see college baseball get more recognition.
Update: Here is press release about the game.